Amorphous Solids Low-Temperature Properties

It is now ten years since it was first convincingly shown that below 1 K the ther­ mal conductivity and the heat capacity of amorphous solids behave in a way which is strikingly different to that of crystalline solids. Since that time there has been a wide variety of experimental and theoretical studies which have not only defined and clarified the low temperature problem more closely, but have also linked these differences between amorphous and crystalline solids to those suggested by older acoustic and thermal experiments (extending up to 100 K). The interest in this somewhat restricted branch of physics lies to a considerable extent in the fact that the differences were so unexpected. It might be thought that as the tempera­ ture, probing frequency, or more generally the energy decreases, a continuum de­ scription in which structural differences between glass and crystal are concealed should become more accurate. In a sense this is true, but it appears that there exists in an amorphous solid a large density of additional excitations which have no counterpart in normal crystals. This book presents a survey of the wide range of experimental investigations of these low energy excitations, together with a re­ view of the various theoretical models put forward to explain their existence and nature.

1. Introduction.- 1.1 Historical Background.- 1.2 Tunneling States.- 1.3 Organization of the Book.- References.- 2. The Vibrational Density of States of Amorphous Semiconductors.- 2.1 The Vibrational Density of States.- 2.2 Experimental Techniques.- 2.3 The Theoretical Problem.- 2.4 Brute Force Theory.- 2.5 More Refined Approaches.- 2.6 The Incorporation of Matrix Elements.- 2.7 Can One Derive Structural Information from g(?)?.- 2.8 A Less Myopic View of the Field.- References.- 3. Low Temperature Specific Heat of Glasses.- 3.1 Review of the Experimental Situation.- 3.2 Comparison with Theoretical Models.- 3.3 Summary and Outlook.- References.- 4. The Thermal Expansion of Glasses.- 4.1 Theoretical Background.- 4.2 The High Temperature Expansion of Vitreous Silica.- 4.3 The Low Temperature Expansion of Glasses.- References.- 5. Thermal Conductivity.- 5.1 Thermal Transport in Crystalline Materials.- 5.2 Thermal Transport in Amorphous Materials.- 5.3 Probing the Localized Excitations.- 5.4 Synopsis.- References.- 6. Acoustic and Dielectric Properties of Glasses at Low Temperatures.- 6.1 General Comments.- 6.2 Acoustic and Dielectric Properties Above 10 K.- 6.3 Acoustic and Dielectric Properties Below 10 K.- 6.4 Theoretical Description of the Acoustic and Dielectric Properties by Two-Level Systems.- 6.5 Comparispn Between Theory and Experiment.- 6.6 Microscopic Description: Tunneling Model.- 6.7 Summary.- References.- 7. Relaxation Times of Tunneling Systems in Glasses.- 7.1 Background.- 7.2 Resonance Dynamics of Two-Level Systems.- 7.3 Experiments Measuring Relaxation Times.- 7.4 Critical Assessment of Data.- 7.5 Conclusions.- References.- 8. Low Frequency Raman Scattering in Glasses.- 8.1 Introductory Comments.- 8.2 Vibrational Raman Spectrum of First Order.- 8.3Quasielastic Spectrum.- 8.4 Conclusion.- References.- Additional References with Titles.- Subject and Material Index.