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pullman a. (curatore) - catalysis in chemistry and biochemistry theory and experiment

Catalysis in Chemistry and Biochemistry Theory and Experiment Proceedings of the Twelfth Jerusalem Symposium on Quantum Chemistry and Biochemistry held in Jerusalem, Israel, April 2–4, 1979




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Dettagli

Genere:Libro
Lingua: Inglese
Pubblicazione: 10/1979
Edizione: 1979





Sommario

The Macromolecular Electrostatic Effect in Biochemical Reactivity of the Nucleic Acids.- Dynamic and Statistical Aspects of Enzyme Action.- Efficiency and Mechanism in Intramolecular Catalysis.- Cryoenzymology in Reverse Micelles.- Theoretical Studies on Models of the Active Site of Carbonic Anhydrase.- The Mechanism of Carbonic Anhydrase — A Solvation Problem?.- A Comparison of the Energetics of Proton Transfer in the Serine and Cysteine ‘Charge Relay’ Systems and the Role of the Protein Electrostatic Potential on the Proton Transfer Energetics.- Hydrolysis by Acetylcholinesterase. Trimethyl and Methyl Subsites.- Creatine Kinase: An Asymmetric Dimer operating by a ‘One-at-a-Time’ Mechanism.- Studies on the Mechanism of Catalysis by Thiamin: Progress and Problems.- The Conformation of Cocarboxylase (Thiamine-Pyrophosphate).- Probing the Mechanism of Binding of the Thiamin Pyrophosphate Co-Enzyme on Yeast Pyruvate Decarboxylase.- Ab Initio Orbital Studies of the Flavins.- Flavin Catalysis, the Experimental Approach.- Molecular Orbital Calculations of Metal Microcluster Properties.- Structure Sensitivity and Supported Platinum Catalysts.- Relation Between Catalytic and Electronic Properties of Transition Metals.- Basic Parameters in Metal-Catalysed Processes: Method of Inverse Titration.- The Chemisorption of Acetylene on the Pt(III) Surface. Extended Hückel Results.- Asymmetric Homogeneous Hydrogenation of Prochiral Olefins and Control of the Metal Configuration in Labile Optically Active Organotransition Metal Complexes.- Homogeneous and Heterogeneous Hydrogen Transfer in Carbinols by Group VIII Metal Catalysts.- The Cooperate Effect of Organomagnesium and Nickel Compounds in the Catalytic Oligomerization of 1,3-Dienes.- Trimethylphosphine Cobaltatescontaining Monoolefin and Dinitrogen Ligands — Model Compounds for Homogeneous Catalysis.- Conformational Transitions of the Membrane-Bound Cholinergic Receptor.- The Catalytic Effect of Hydrogen Bonding upon Epoxide Ring-Opening.- A Comparison of Dioxygen Activation by Biochemical and Synthetic Polymeric Chemical Systems.- Surface and End Effects in the Electronic Structure of Crystals and Polymers.- Some Aspects of Asymmetric Induction in Addition Reactions to Olefins.- The Catalytic Function of Anthraquinones in the Photooxidation of Chloride to Chlorine.- Tetraphenylporphyrin Complexes as Chemical, Photo- and Electro-Catalysts.- Index of Subjects.- Index of Names.










Altre Informazioni

ISBN:

9789027710390

Condizione: Nuovo
Collana: Jerusalem Symposia
Dimensioni: 254 x 178 mm
Formato: Copertina rigida
Illustration Notes:X, 390 p.
Pagine Arabe: 390
Pagine Romane: x


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